Product ID:1,2,4-TRICHLOROBENZENE, O-689
MSDS Date:09/01/1988
FSC:6810
NIIN:00N067818
MSDS Number: CBGNP

CHEM SERVICE INC

WEST CHESTER, PA 19381
US

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

CHEM SERVICE, INC

599 WEST CHESTER, PA 19301-9650 US

Telephone: 610-692-3026

Cage: 8Y898

BENZENE, 1,2,4-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA

CAS: 120-82-1

RTECS: DC2100000

OSHA PEL 5 PPM, C

ACGIH TLV: 5 PPM, C

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT): 756 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN CAUSE EYE AND SKIN
IRRITATION. CAN BE HARMFUL IF ABSORBED THROUGH SKIN, INHALED, OR
SWALLOWED. CAN BE IRRITATING TO MUCOUS MEMBRANES. CHRONIC:
PROLONGED EXPOSURE MAY CAUSE NAUSEA, HEADACHE, DIZZINESS, AND/OR
EYE DAMAGE. CAN CAUSE KIDNEY INJURY. CAN CAUSE GASTROINTESTINAL
DISTURBANCES.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:AN ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFT OF
POIS. IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE
CAN BE OBTAINED FROM POIS CTL CTR. EYES: FLUSH CONTINUOUSLY W/WATER
FOR AT LE AST 15 MIN. SKIN: FLUSH W/WATER FOR 15-20 MIN. IF NO
BURNS HAVE OCCURRED, USE SOAP & WATER TO CLEANSE SKIN. INHAL:
REMOVE TO FRESH AIR. ADMIN OXYGEN IF DFCLT BRTHG. IF BRTHG HAS
STOPPED, (SUP DAT)

Flash Point:234F,112C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR
MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR
DISPOSAL. WASH CONTAMINATE D SURFACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS. AVOID DIRECT PHYSICAL CONTACT! USE APPROPRIATE OSHA/MSMA
APPROVED SAFETY EQUIPMENT.
Other Precautions:AVOID CONT W/SKIN, EYES, & CLTHG. KEEP TIGHTLY CLSD &
STORE IN COOL DRY PLACE. STORE ONLY W/COMPATIBLE CHEM. PERS NOT
SPECIFICALLY & PROPERLY TRAINED SHOULD NOT HANDLE THIS CHEM/ITS
CONTR. THIS PROD I S FURNISHED FOR LAB USE ONLY! (SUP DAT)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC: ADMIN ARTF RESP. IF PATIENT IN CARD ARREST, ADMIN CPR.
CONTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSIST HAS ARRIVED.
INGEST: CALL MD IMMED . OTHER PREC: THIS PROD MAY NOT BE US ED AS
DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PRODS, FOOD ADDITIVES/AS
HOUSEHOLD CHEMICALS.

Boiling Pt:B.P. Text:417F,214C
Melt/Freeze Pt:M.P/F.P Text:60.8F,16.0C
Spec Gravity:1.454
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
DECOMPOSITION PRODUCTS ARE CORROSIVE.

Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.